Let's call the unknown angles ∠ A and ∠ B. We know that ∠ A and ∠ B are complementary and, therefore, the sum of their measures is 90^(∘).
m∠ A + m∠ B = 90
We are told that the bigger angle is twice as large as the smaller angle. Assume that ∠ A is the smaller angle and let's call its measure x. Then we have the following expressions for the measures of the unknown angles.
m∠ A =& x
m∠ B =& 2x
Now we can substitute these values into our equation and solve for x.