Vertical angles are formed by two intersecting lines, so we should look for intersecting lines on the diagram. One possibility, along with the corresponding vertical angle pairs, is highlighted on the diagram below.
It appears that ∠DFB is obtuse, but can this be guaranteed based on the information given on the diagram? Notice that the marker at D indicates that AE is perpendicular to DC.
This perpendicularity means that triangle DFE is a right triangle, so it can be assumed that ∠DFE is acute. Since ∠DFE and ∠DFB are supplementary angles, this also means that ∠DFB is obtuse. Hence, ∠CFE and ∠DFB are two obtuse vertical angles.